Manipulation of Phosphorescence Efficiency of Cyclometalated Iridium Complexes by Substituted o-Carboranes
DC Field | Value | Language |
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dc.contributor.author | Lee, Young Hoon | - |
dc.contributor.author | Park, Jihyun | - |
dc.contributor.author | Jo, Song-Jin | - |
dc.contributor.author | Kim, Miyoung | - |
dc.contributor.author | Lee, Junseong | - |
dc.contributor.author | Lee, Sang Uck | - |
dc.contributor.author | Lee, Min Hyung | - |
dc.date.accessioned | 2021-06-22T20:25:38Z | - |
dc.date.available | 2021-06-22T20:25:38Z | - |
dc.date.issued | 2015-01 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/18891 | - |
dc.description.abstract | A series of [(C<^>N)(2)Ir(acac)] complexes [{5-(2-R-CB)ppy}(2)Ir(acac)] (3a-3g; acac= acetylacetonate, CB=o-carboran-1-yl, ppy=2-phenylpyridine; R=H (3a), Me (3b), iPr (3c), iBu (3d), Ph (3e), CF3C6H4 (3f), C6F5 (3g)) with various 2-R-substituted o-carboranes at the 5-position in the phenyl ring of the ppy ligand were prepared. X-ray diffraction studies revealed that the carboranyl C-C bond length increases with increasing steric and electron-withdrawing effects from the 2-R substituents. Although the absorption and emission wavelengths of the complexes are almost invariant to the change of 2-R group, the phosphorescence quantum efficiency varies from highly emissive (Phi(PL) approximate to 0.80 for R=H, alkyl) to poorly emissive (R=aryl) depending on the 2-R group and the polarity of the medium. Theoretical studies suggest that 1) the almost nonemissive nature of the 2-aryl-substituted complexes is mainly attributable to the large contribution to the LUMO in the S-1 excited state from an o-carborane unit and 2) the variation in the C-C bond length between the S-0 and T-1 state structures increases with increasing steric (2-alkyl) and electronic effects (2-aryl) of the 2-R substituent and the polarity of the solvent. The solution-processed electroluminescence (EL) devices that incorporated 3b and 3d as emitters displayed higher performance than the device based on the parent [(ppy) 2Ir(acac)] complex. Along with the high phosphorescence efficiency, the bulkiness of the 2-R-o-carborane unit is shown to play an important role in improving device performance. | - |
dc.format.extent | 10 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Manipulation of Phosphorescence Efficiency of Cyclometalated Iridium Complexes by Substituted o-Carboranes | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/chem.201405433 | - |
dc.identifier.scopusid | 2-s2.0-84921342777 | - |
dc.identifier.wosid | 000348510100031 | - |
dc.identifier.bibliographicCitation | Chemistry - A European Journal, v.21, no.5, pp 2052 - 2061 | - |
dc.citation.title | Chemistry - A European Journal | - |
dc.citation.volume | 21 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 2052 | - |
dc.citation.endPage | 2061 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | LIGHT-EMITTING DEVICES | - |
dc.subject.keywordPlus | AGGREGATION-INDUCED EMISSION | - |
dc.subject.keywordPlus | C-C DISTANCE | - |
dc.subject.keywordPlus | PHOTOPHYSICAL PROPERTIES | - |
dc.subject.keywordPlus | IR(III) COMPLEXES | - |
dc.subject.keywordPlus | ELECTROPHOSPHORESCENT DEVICES | - |
dc.subject.keywordPlus | BLUE PHOSPHORESCENCE | - |
dc.subject.keywordPlus | RED PHOSPHORESCENCE | - |
dc.subject.keywordPlus | POLYHEDRAL BORANES | - |
dc.subject.keywordPlus | CHARGE-TRANSFER | - |
dc.subject.keywordAuthor | carboranes | - |
dc.subject.keywordAuthor | iridium | - |
dc.subject.keywordAuthor | organic light-emitting diodes | - |
dc.subject.keywordAuthor | photophysics | - |
dc.subject.keywordAuthor | quantum efficiency | - |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201405433 | - |
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