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Effect of CaF(2)on Phosphorus Refining from Molten Steel by Electric Arc Furnace Slag using Direct Reduced Iron (DRI) as a Raw Material

Authors
Oh, Min KyoKim, Tae SungPark, Joo Hyun
Issue Date
Dec-2020
Publisher
ASM International
Citation
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, v.51, no.6, pp 3028 - 3038
Pages
11
Indexed
SCIE
SCOPUS
Journal Title
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume
51
Number
6
Start Page
3028
End Page
3038
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/1929
DOI
10.1007/s11663-020-01957-y
ISSN
1073-5615
1543-1916
Abstract
The effect of CaF(2)addition on dephosphorization reaction between molten steel and electric arc furnace (EAF) slag using direct reduced iron (DRI) at 1823 K (1550 degrees C) was investigated. Basicity, the thermodynamic parameter affecting the removal capacity of phosphorus (i.e.,phosphate capacity), decreased using DRI due to an increased SiO(2)concentration in the slag. To minimize slag volume and maximize dephosphorization efficiency, the CaF(2)was added to the slag. As CaF(2)content increased (0 to 10 mass pct), dephosphorization efficiency also increased. Thermodynamic analysis in conjunction with slag structural studies using Raman spectroscopy were conducted to explain the complicated phenomena. The results exhibited that even 5 to 6 mass pct CaF(2)can improve the dephosphorization efficiency when DRI is used as raw material in an EAF process.
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Park, Joo Hyun
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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