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Pd nanoparticles immobilized on PNIPAMhalloysite: highly active and reusable catalyst for Suzuki-Miyaura coupling reactions in water
- Issue Date
- Mar-2014
- Publisher
- John Wiley & Sons Inc.
- Keywords
- Suzuki-Miyaura reactions; Pd nanoparticles; PNIPAM-halloysite nanocomposite; reusable catalysts; water
- Citation
- Applied Organometallic Chemistry, v.28, no.3, pp 156 - 161
- Pages
- 6
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Applied Organometallic Chemistry
- Volume
- 28
- Number
- 3
- Start Page
- 156
- End Page
- 161
- ISSN
- 0268-2605
1099-0739
- Abstract
- Poly(N-isopropylacrylamide)-halloysite (PNIPAM-HNT) nanocomposites exhibited inverse temperature solubility with a lower critical solution temperature (LCST) in water. Palladium (Pd) nanoparticles were anchored on PNIPAM-HNT nanocomposites with various amounts of HNT from 5 to 30wt%. These Pd catalysts exhibited excellent reactivities for Suzuki-Miyaura coupling reactions at 50-70 degrees C in water. In particular, Pd anchored PNIPAM/HNT (95:5 w/w ratio) nanocomposites showed excellent recyclability up to 10 times in 96% average yield by simple filtration. Copyright (c) 2014 John Wiley & Sons, Ltd.
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Related Researcher
- LEE, YONG WOO
- ERICA 공학대학 (ERICA 에너지바이오학과)