바나듐계 촉매상에서 암모니아를 이용한 질소산화물의 환원반응속도에 수분이 미치는 영향에 관한 연구
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김영득 | - |
dc.contributor.author | 정수진 | - |
dc.contributor.author | 김우승 | - |
dc.date.accessioned | 2021-06-23T08:28:10Z | - |
dc.date.available | 2021-06-23T08:28:10Z | - |
dc.date.created | 2021-01-22 | - |
dc.date.issued | 2012-11 | - |
dc.identifier.issn | 1225-6382 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/34337 | - |
dc.description.abstract | The main and side reactions of the three selective catalytic reduction (SCR) reactions with ammonia over a vanadium-based catalyst have been investigated using synthetic gas mixtures in the temperature range of 170~590°C. The three SCR reactions are standard SCR with pure NO, fast SCR with an equimolar mixture of NO and NO2, and NO2 SCR with pure NO2. Vanadium based catalyst has no significant activity in NO oxidation to NO2, while it has high activity for NO2 decomposition at high temperatures. The selective catalytic oxidation of ammonia and the formation of nitrous oxide compete with the SCR reactions at the high temperatures. Water strongly inhibits the selective catalytic oxidation of ammonia and the formation of nitrous oxide, thus increasing the selectivity of the SCR reactions. However, the presence of water inhibits the SCR activity, most pronounced at low temperatures. In this study, the experimental results are analyzed by means of a dynamic one-dimensional isothermal heterogeneous plug-flow reactor (PFR) model according to the Eley-Rideal mechanism. | - |
dc.language | 한국어 | - |
dc.language.iso | ko | - |
dc.publisher | 한국자동차공학회 | - |
dc.title | 바나듐계 촉매상에서 암모니아를 이용한 질소산화물의 환원반응속도에 수분이 미치는 영향에 관한 연구 | - |
dc.title.alternative | Effect of Water on the Kinetics of Nitric Oxides Reduction by Ammonia over V-based Catalyst | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | 김우승 | - |
dc.identifier.doi | 10.7467/KSAE.2012.20.6.073 | - |
dc.identifier.bibliographicCitation | 한국자동차공학회 논문집, v.20, no.6, pp.73 - 82 | - |
dc.relation.isPartOf | 한국자동차공학회 논문집 | - |
dc.citation.title | 한국자동차공학회 논문집 | - |
dc.citation.volume | 20 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 73 | - |
dc.citation.endPage | 82 | - |
dc.type.rims | ART | - |
dc.identifier.kciid | ART001706333 | - |
dc.description.journalClass | 2 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | kci | - |
dc.subject.keywordAuthor | SCR(선택적 촉매환원) | - |
dc.subject.keywordAuthor | Ammonia(암모니아) | - |
dc.subject.keywordAuthor | NOX reduction(질소산화물 저감) | - |
dc.subject.keywordAuthor | Water(수분) | - |
dc.subject.keywordAuthor | Mathematical modeling(수학적 모델링) | - |
dc.identifier.url | https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART001706333 | - |
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