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In-situ observation of dynamic interfacial phenomena between CaO-(SiO2 or Al2O3) slag and Fe-11%Cr alloy near the MgO-6%C refractory at 1823 K

Authors
Shin, MinsooCho, SeungyounLee, JoonhoPark, Joo-Hyun
Issue Date
Jun-2010
Publisher
대한금속·재료학회
Keywords
oxides; purification; wetting; image analysis; dynamic interfacial phenomena
Citation
Metals and Materials International, v.16, no.3, pp.495 - 499
Indexed
SCIE
SCOPUS
KCI
Journal Title
Metals and Materials International
Volume
16
Number
3
Start Page
495
End Page
499
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/39771
DOI
10.1007/s12540-010-0623-5
ISSN
1598-9623
Abstract
We investigated dynamic interfacial phenomena at the slag-metal-refractory three-phase interface using a high temperature X-ray radiographic technique. Dynamic movement of the metal-slag line between Fe-11%Cr alloy and CaO-(SiO2 or Al2O3) slag was observed near the MgO-6%C refractory at 1823 K. We observed corresponding local corrosion of the refractory with CaO-SiO2 slag but it was negligible with CaO-Al2O3 slag. From a thermodynamic perspective, the Marangoni convection at the slag-metal-refractory interface is not the dominant factor determining the corrosion rate of the MgO-C refractory. Rather, it is the large solubility limit and the mass transfer in the slag phase.
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ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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