Isoreticular Metal-Organic Polyhedral Networks Based on 5-Connecting Paddlewheel Motifs
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chun, Hyungphil | - |
dc.contributor.author | Jung, Heejin | - |
dc.contributor.author | Seo, Jinwoo | - |
dc.date.accessioned | 2021-06-23T15:41:30Z | - |
dc.date.available | 2021-06-23T15:41:30Z | - |
dc.date.created | 2021-01-21 | - |
dc.date.issued | 2009-03 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/41351 | - |
dc.description.abstract | A metal-organic polyhedral network with a unique 5-connected topology is expanded into a series using different metal ions or dicarboxylate ligands. The prototype material (ZmID), [Zn-4(MiP)(4)(dabco)(OH2)(2)] (mip = 5-methylisophthalate, dabco = diazabicyclo[2.2.2]octane), is based on 5-connecting paddlewheel motifs and possesses large cage-like pores (8-20 angstrom diameter). The metal ion is replaced by Co2+ and/or the dicarboxylate by isophthalate (ip) or 2,7-naphthalenedicarboxylate (2,7-ndc) to give isoreticular frameworks [Zn-4(ip)(4)(dabco)(OH2)(2)] (ZID), [Co4O4(dabco)(OH2)(2)] (CID), and [Zn-4(2,7-ndc)(4)(dabco)(OH2)(2)] (ZND). X-ray powder diffraction and gas sorption studies reveal that ZID and CID have sustainable pore structures and show higher N-2 uptakes than ZmID. ZND is found unstable with respect to the removal of guest solvents. ZmID, ZID, and CID are all similar in terms of the H-2 sorption capacities (1.4-1.5 wt % at 77 K and 1 bar) and isosteric heat of H2 adsorption (6-7 kJ/mol at low coverage). | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | American Chemical Society | - |
dc.title | Isoreticular Metal-Organic Polyhedral Networks Based on 5-Connecting Paddlewheel Motifs | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Chun, Hyungphil | - |
dc.identifier.doi | 10.1021/ic801784j | - |
dc.identifier.scopusid | 2-s2.0-64549126518 | - |
dc.identifier.wosid | 000263667700033 | - |
dc.identifier.bibliographicCitation | Inorganic Chemistry, v.48, no.5, pp.2043 - 2047 | - |
dc.relation.isPartOf | Inorganic Chemistry | - |
dc.citation.title | Inorganic Chemistry | - |
dc.citation.volume | 48 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 2043 | - |
dc.citation.endPage | 2047 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | COORDINATION-FRAMEWORK | - |
dc.subject.keywordPlus | RETICULAR CHEMISTRY | - |
dc.subject.keywordPlus | SORPTION PROPERTIES | - |
dc.subject.keywordPlus | GAS-ADSORPTION | - |
dc.subject.keywordPlus | H-2 ADSORPTION | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | MOFS | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | TOPOLOGY | - |
dc.subject.keywordAuthor | RETICULAR CHEMISTRY | - |
dc.subject.keywordAuthor | TOPOLOGY | - |
dc.subject.keywordAuthor | COORDINATION-FRAMEWORK MATERIALS | - |
dc.subject.keywordAuthor | DESIGN | - |
dc.subject.keywordAuthor | GAS-ADSORPTION | - |
dc.subject.keywordAuthor | CATENATION | - |
dc.subject.keywordAuthor | H-2 ADSORPTION | - |
dc.subject.keywordAuthor | MOFS | - |
dc.subject.keywordAuthor | HYDROGEN STORAGE | - |
dc.subject.keywordAuthor | SORPTION PROPERTIES | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ic801784j | - |
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