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Hydrogenation and Annealing Effects in n-Type ZnO Bulk Samples

Authors
Shin, Y. H.Kim, M. D.Oh, J. E.Han, M. S.Kim, S. G.Chung, K. S.
Issue Date
Nov-2008
Publisher
KOREAN PHYSICAL SOC
Keywords
ZnO; Photoluminescence; Hydrogenation; Yellow band; Green band; Passivation
Citation
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, v.53, no.5, pp 2504 - 2507
Pages
4
Indexed
SCIE
SCOPUS
KCI
Journal Title
JOURNAL OF THE KOREAN PHYSICAL SOCIETY
Volume
53
Number
5
Start Page
2504
End Page
2507
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/42068
DOI
10.3938/jkps.53.2504
ISSN
0374-4884
1976-8524
Abstract
Photoluminescence (PL) measurements were performed on as-grown, hydrogenated and hydrogenated and annealed n-type ZnO bulk samples in order to investigate the origins of their yellow and green emission bands. After hydrogenation, the defect-related peak at 2.10 eV was no longer present in the PL spectrum at room temperature, the peak intensity at 2.43 eV was unchanged and the intensity of the emission peak at 3.27 eV was strongly increased. These results indicate that the yellow band emission is due to oxygen vacancies because the emission peak at 2.10 eV disappears when these vacancies are passivated by hydrogen atoms. The emission peak at 2.43 eV originates from complexes between oxygen vacancies and other crystal defects. We discuss the effects of hydrogenation and annealing on the ZnO bulk samples.
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