Efficient hydrogen sorption in 8-connected MOFs based on trinuclear pinwheel motifs
DC Field | Value | Language |
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dc.contributor.author | Chun, Hyungphil | - |
dc.contributor.author | Jung, Heejin | - |
dc.contributor.author | Koo, Gumae | - |
dc.contributor.author | Jeong, Heondo | - |
dc.contributor.author | Kim, Dong-Kook | - |
dc.date.accessioned | 2021-06-23T17:38:17Z | - |
dc.date.available | 2021-06-23T17:38:17Z | - |
dc.date.created | 2021-01-21 | - |
dc.date.issued | 2008-06 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/42373 | - |
dc.description.abstract | Two new metal-organic frameworks based on trinuclear pinwheel motifs are prepared using dicarboxylate and diamine ligands. The structure of (CO3(bdC)(3)(dabco)] (1) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2]octane) is described as pillared layers, whereas [Co-3(ndc)(3)(dabco)] (2) (ndc = 2,6-naphthalenedicarboxylate) forms a variation of primitive cubic net with 3D connected pores. The two 8-connected MOFs are thermally stable at 160 and 250 degrees C for 1 and 2 respectively in the air and possess corrugated channels owing to the high connectivities of the secondary building unit. As a result, they show highly efficient hydrogen sorption capabilities. Especially, a high hydrogen uptake (2.45 wt % at 77 K and 1 bar) is observed for 2 that has the unique combination of high surface area and small portals. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | American Chemical Society | - |
dc.title | Efficient hydrogen sorption in 8-connected MOFs based on trinuclear pinwheel motifs | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Chun, Hyungphil | - |
dc.identifier.doi | 10.1021/ic800274w | - |
dc.identifier.scopusid | 2-s2.0-46949098348 | - |
dc.identifier.wosid | 000256591400042 | - |
dc.identifier.bibliographicCitation | Inorganic Chemistry, v.47, no.12, pp.5355 - 5359 | - |
dc.relation.isPartOf | Inorganic Chemistry | - |
dc.citation.title | Inorganic Chemistry | - |
dc.citation.volume | 47 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 5355 | - |
dc.citation.endPage | 5359 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | COORDINATION POLYMERS | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ic800274w | - |
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