Application of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate
DC Field | Value | Language |
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dc.contributor.author | Kyong, Jin Burm | - |
dc.contributor.author | Won, Hoshik | - |
dc.contributor.author | Kevill, Dennis N. | - |
dc.date.accessioned | 2021-06-23T23:41:21Z | - |
dc.date.available | 2021-06-23T23:41:21Z | - |
dc.date.created | 2021-02-01 | - |
dc.date.issued | 2005-01 | - |
dc.identifier.issn | 1661-6596 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/46149 | - |
dc.description.abstract | Application of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate in a variety of pure and binary solvents indicates an addition-elimination pathway in the majority of the solvents but an ionization pathway in the solvents of highest ionizing power and lowest nucleophilicity. For methanolysis, a solvent deuterium isotope effect of 2.17 is compatible with the incorporation of general-base catalysis into the substitution process. Activation parameters are consistent with the duality of mechanism. Very modest positive salt effects are observed on adding chloride or bromide salts to the ethanolysis. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | Multidisciplinary Digital Publishing Institute (MDPI) | - |
dc.title | Application of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Won, Hoshik | - |
dc.identifier.doi | 10.3390/i6010087 | - |
dc.identifier.scopusid | 2-s2.0-14644406279 | - |
dc.identifier.wosid | 000230388200009 | - |
dc.identifier.bibliographicCitation | International Journal of Molecular Sciences, v.6, no.1-2, pp.87 - 96 | - |
dc.relation.isPartOf | International Journal of Molecular Sciences | - |
dc.citation.title | International Journal of Molecular Sciences | - |
dc.citation.volume | 6 | - |
dc.citation.number | 1-2 | - |
dc.citation.startPage | 87 | - |
dc.citation.endPage | 96 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Biochemistry & Molecular Biology | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Biochemistry & Molecular Biology | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | SOLVENT NUCLEOPHILICITY SCALE | - |
dc.subject.keywordPlus | TERT-BUTYL CHLORIDE | - |
dc.subject.keywordPlus | SN2-SN1 SPECTRUM | - |
dc.subject.keywordPlus | NITROBENZOYL CHLORIDE | - |
dc.subject.keywordPlus | DUAL PATHWAYS | - |
dc.subject.keywordPlus | RATES | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | PRODUCT | - |
dc.subject.keywordPlus | ATTACK | - |
dc.subject.keywordPlus | PHOSPHOROCHLORIDATE | - |
dc.subject.keywordAuthor | n-propyl chloroformate | - |
dc.subject.keywordAuthor | addition-elimination | - |
dc.subject.keywordAuthor | ionization | - |
dc.subject.keywordAuthor | solvent isotope effect | - |
dc.subject.keywordAuthor | Grunwald-Winstein equation | - |
dc.identifier.url | https://www.mdpi.com/1422-0067/6/1/87 | - |
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