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The effects of impeller characteristics in the hydrogenation of aniline on Ru/C catalyst

Authors
Cho, Hong-BaekPark, Yeung Ho
Issue Date
Mar-2003
Publisher
한국화학공학회
Keywords
Hydrogen Concentration; Hydrogenation of Aniline; Impeller Characteristics; Product Selectivity; Reaction Rate
Citation
Korean Journal of Chemical Engineering, v.20, no.2, pp.262 - 267
Indexed
SCIE
SCOPUS
Journal Title
Korean Journal of Chemical Engineering
Volume
20
Number
2
Start Page
262
End Page
267
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/46735
DOI
10.1007/BF02697238
ISSN
0256-1115
Abstract
Effects of impeller characteristics have been studied in the hydrogenation of aniline on Ru/C catalyst. Dual impellers were employed and the experiments were performed at 300 rpm using a lab-scale reactor. Reaction with disk turbines (DT) resulted in the higher cyclohexylamine (CHA) selectivity and higher reaction rate compared to that with pitched blade turbines (PBT). When a combination of PBT and DT impellers was employed, high product selectivity and reaction rate were obtained and the selectivity was maintained constant. Changes in the product selectivity with the impeller geometry were explained in terms of the relative rates of the side reactions depending on the hydrogen concentration in the reaction mixture.
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COLLEGE OF ENGINEERING SCIENCES > DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING > 1. Journal Articles

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Hong-Baek, Cho
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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