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Use of Industrial Waste (Al-Dross, Red Mud, Mill Scale) as Fluxing Agents in the Sulfurization of Fe-Ni-Cu-Co Alloy by Carbothermic Reduction of Calcium Sulfate

Authors
Heo, Jung HoJeong, Eui HyukNam, Chul WooPark, Kyung HoPark, Joo Hyun
Issue Date
Jun-2018
Publisher
ASM International
Keywords
ALUMINUM DROSS; BEHAVIOR
Citation
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, v.49, no.3, pp.939 - 943
Indexed
SCIE
SCOPUS
Journal Title
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume
49
Number
3
Start Page
939
End Page
943
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/6186
DOI
10.1007/s11663-018-1217-8
ISSN
1073-5615
Abstract
The use of industrial waste [mill scale (MS), red mud (RM), Al-dross (AD)] as fluxing agents in the sulfurization of Fe-Ni-Cu-Co alloy to matte (Fe-Ni-Cu-Co-S) by carbothermic reduction of CaSO4 was investigated at 1673 K (1400 degrees C). The sulfurization efficiency (SE) was 76 (+/- 2) pct at RM or AD single fluxing. However, SE drastically increased to approximately 89 pct at a '5AD + 5MS' combination, which was equivalent to reagent-grade chemical '5Al(2)O(3) + 5Fe(2)O(3)' fluxing (SE = 88 pct). The present results can be used to improve the cost-effective recovery of rare metals (Ni and Co) from deep sea manganese nodules. (C) The Minerals, Metals & Materials Society and ASM International 2018
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Park, Joo Hyun
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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