Controllable Synthesis of a Highly Ordered Polymeric Structure Assembled from Cobalt-Cluster-based Racemic Supramolecules
DC Field | Value | Language |
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dc.contributor.author | Mai, Hien Duy | - |
dc.contributor.author | Lee, Inme | - |
dc.contributor.author | Yoo, Hyojong | - |
dc.date.accessioned | 2021-06-22T13:02:02Z | - |
dc.date.available | 2021-06-22T13:02:02Z | - |
dc.date.created | 2021-01-22 | - |
dc.date.issued | 2018-08 | - |
dc.identifier.issn | 1861-4728 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/7885 | - |
dc.description.abstract | Metallosupramolecule-based polymeric platforms with high degrees of hierarchy and tailorable functionalities are of great interests because of their unique morphologies and potential applications. Herein, the controllable synthesis of a highly-ordered polymeric structure, {[M,P-Co8(PDA)6(HIP)3(DMF)5(H2O)]3-[Co(DMF)(H2O)2]} (1) (PDA=2,6-pyridinedicarboxylate, HIP=5-hydroxyisophthalate, DMF=dimethylformamide) with unique topology is reported. The solid-state structure of 1 reveals that it is alternately and periodically assembled from racemic supramolecular monomers to form a zigzag-shaped polymeric strand. Discrete racemic supramolecules (2) with topologies similar to those of monomeric species of 1 are also controllably synthesized in a separate reaction. Formation of intermolecular hydrogen bonds between supramolecules associated with hydroxyl groups of HIPs are critical for the unique solid-state packing geometries of 1 and 2. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | Wiley - V C H Verlag GmbbH & Co. | - |
dc.title | Controllable Synthesis of a Highly Ordered Polymeric Structure Assembled from Cobalt-Cluster-based Racemic Supramolecules | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yoo, Hyojong | - |
dc.identifier.doi | 10.1002/asia.201800837 | - |
dc.identifier.scopusid | 2-s2.0-85050632523 | - |
dc.identifier.wosid | 000445894800010 | - |
dc.identifier.bibliographicCitation | Chemistry - An Asian Journal, v.13, no.15, pp.1915 - 1919 | - |
dc.relation.isPartOf | Chemistry - An Asian Journal | - |
dc.citation.title | Chemistry - An Asian Journal | - |
dc.citation.volume | 13 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 1915 | - |
dc.citation.endPage | 1919 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | Cobalt | - |
dc.subject.keywordPlus | Dimethylformamide | - |
dc.subject.keywordPlus | Hydrogen bonds | - |
dc.subject.keywordPlus | Organic solvents | - |
dc.subject.keywordPlus | Topology | - |
dc.subject.keywordPlus | Controllable synthesis | - |
dc.subject.keywordPlus | Highly ordered assemblies | - |
dc.subject.keywordPlus | Intermolecular hydrogen bonds | - |
dc.subject.keywordPlus | Metallosupramolecule | - |
dc.subject.keywordPlus | Polymeric structures | - |
dc.subject.keywordPlus | Solid-state structures | - |
dc.subject.keywordPlus | Supramolecules | - |
dc.subject.keywordPlus | Unique morphologies | - |
dc.subject.keywordPlus | Polymers | - |
dc.subject.keywordAuthor | highly-ordered assembly | - |
dc.subject.keywordAuthor | intermolecular hydrogen bond | - |
dc.subject.keywordAuthor | polymeric structures | - |
dc.subject.keywordAuthor | racemic supramolecules | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/asia.201800837 | - |
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