Feasibility tests of -SO3H/-SO3--functionalized magnesium phyllosilicate [-SO3H/-SO3- MP] for environmental and bioenergy applications
- Authors
- Kang, Hyun Gu; Lee, Kyoung Min; Choi, Saehae; Nam, Bora; Choi, Sun-A; Lee, Soon-Chang; Park, Ji-Yeon; Lee, Go-Woon; Lee, Hyun Uk; Lee, Young-Chul
- Issue Date
- Jul-2015
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- RSC ADVANCES, v.5, no.78, pp.63271 - 63277
- Journal Title
- RSC ADVANCES
- Volume
- 5
- Number
- 78
- Start Page
- 63271
- End Page
- 63277
- URI
- https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/11840
- DOI
- 10.1039/c5ra07390a
- ISSN
- 2046-2069
- Abstract
- We have prepared a simplewater-solubilized, transparent, and anionic clay. -SH-functionalized magnesium phyllosilicate [-SH MP] was easily oxidized into -SO3H/-SO3--functionalized magnesium phyllosilicate [-SO3H/-SO3- MP] by treatment of 5.0% H2O2 at 60 degrees C for 24 hours, showing a pH of similar to 2.0. These water-solubilized and anionic nanoparticles (NPs) were tested with organo-building blocks of -SO3H/-SO3- MP for removal of cationic pollutant dye (methylene blue) and heavy metals (Cd2+ and Pb2+). Furthermore, interactions of ubiquitous humic acid (HA) with -SO3H/-SO3- MP were removed due to an ion exchange mechanism. For bioenergy applications, glucose conversion from cellulose was tested, focusing on Bronsted acid-rich sites in -SO3H/-SO3- MP.
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