Coordination-Driven Self-Assembly of Arene-Ruthenium Compounds
- Authors
- Mishra, Anurag; Kang, Se Chan; Chi, Ki-Whan
- Issue Date
- 14-Oct-2013
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Supramolecular chemistry; Self-assembly; Ruthenium; Antitumor agents; Biological activity
- Citation
- EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, v.2013, no.30, pp.5222 - 5232
- Journal Title
- EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Volume
- 2013
- Number
- 30
- Start Page
- 5222
- End Page
- 5232
- URI
- https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/14217
- DOI
- 10.1002/ejic.201300729
- ISSN
- 1434-1948
- Abstract
- The coordination-driven self-assembly of N-donor ligands with dinuclear arene-ruthenium building blocks has allowed the construction of a wide range of cationic supramolecules with different architectures and functionalities. These supramolecules include (1) hexacationic molecular metallaprisms in which the size of the cycle and type of the arene-ruthenium acceptor and organic linker influence the antitumor behavior of the resulting self-assembly, and (2) tetracationic molecular metallarectangles, which have host-guest capabilities and allow sensing of biological properties. This report covers the synthetic and structural aspects of these coordination-driven self-assembled supramolecules as well as their most promising applications, with a particular focus on potential biological, sensing, and host-guest applications.
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