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Facile synthesis of chitosan-mediated gold nanoflowers as surface-enhanced Raman scattering (SERS) substrates

Authors
Tran Thi NhungBu, YanruLee, Sang-Wha
Issue Date
15-Jun-2013
Publisher
ELSEVIER SCIENCE BV
Keywords
Crystal morphology; Nanostructures; Growth from solutions; Metals; Nanomaterials
Citation
JOURNAL OF CRYSTAL GROWTH, v.373, pp.132 - 137
Journal Title
JOURNAL OF CRYSTAL GROWTH
Volume
373
Start Page
132
End Page
137
URI
https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/14473
DOI
10.1016/j.jcrysgro.2012.09.042
ISSN
0022-0248
Abstract
Metal nanoflowers are the most attractive substrate for surface-enhanced Raman scattering (SERS) due to many hot-spots on their surfaces. This paper worked on the facile fabrication of gold nanoflowers (AuNFs) through the reduction of HAuCl4 with ascorbic acid in the presence of chitosan polymers. The resulting AuNFs exhibited controllable size, morphology, and plasmon-derived absorption by adjusting the chitosan concentration, pH of the solution, and dosage amounts of ascorbic acid. X-ray diffraction (XRD) patterns showed face-centered cubic (fcc) structure for these nanoflowers. As-prepared AuNFs were successfully employed as an active SERS substrate in the sensitive detection of 2-chlorothiophenol (10(-4) M). (C) 2012 Elsevier B.V. All rights reserved.
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