Synthesis of Diblock Codendrimer by Double Click Chemistry
- Authors
- Lee, Jae Wook; Han, Seung Choul; Ji, Won Ho; Jin, Sung-Ho; Kim, Ji Hyeon
- Issue Date
- 20-Dec-2012
- Publisher
- KOREAN CHEMICAL SOC
- Keywords
- Alkyne; Azide; Click reaction; Diblock dendrimer; Triazole
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.33, no.12, pp.4103 - 4108
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 33
- Number
- 12
- Start Page
- 4103
- End Page
- 4108
- URI
- https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/15927
- DOI
- 10.5012/bkcs.2012.33.12.4103
- ISSN
- 0253-2964
- Abstract
- Efficient double click methods for the synthesis of diblock codendrimers were developed. The synthetic strategy involved the sequential click reactions between an alkyne and an azide. The short core building block, 1,4-diazidobutane, was chosen to serve as the azide functionalities for dendrimer growth via click reactions with the alkyne-functionalized PAMAM dendrons as hydrophilic dendron and alkyne-functionalized Frechet-type dendrons as hydrophobic dendron. The structure of diblock codendrimers was confirmed by H-1 and C-13 NMR spectroscopy, IR spectroscopy, mass spectrometry, and GPC analysis.
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Collections - 공과대학 > 화공생명공학과 > 1. Journal Articles
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