Metal-free late-stage C(sp(2))-H functionalization of N-aryl amines with various sodium salts
DC Field | Value | Language |
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dc.contributor.author | Mudithanapelli, Chandrashekar | - |
dc.contributor.author | Kim, Mi-hyun | - |
dc.date.available | 2020-03-03T06:42:38Z | - |
dc.date.created | 2020-02-24 | - |
dc.date.issued | 2020-01 | - |
dc.identifier.issn | 1477-0520 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/17625 | - |
dc.description.abstract | Metal-free consecutive C(sp(2))-X (X = Cl, Br, S, N) bond formations of N-aryl amines (cyclic, fused, carbamate, and aminium radicals) were achieved under mild conditions using [bis(trifluoroacetoxy)iodo]benzene (PIFA) and simple nonharmful sodium salts. This direct and selective C(sp(2))-H functionalization showed excellent functional group compatibility, cost effectiveness, and late-stage applicability for the synthesis of biologically active natural products. Two mechanisms were proposed to explain the ortho- or para-preference, as well as the accelerating effect of CH3NO2. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | ORGANIC & BIOMOLECULAR CHEMISTRY | - |
dc.title | Metal-free late-stage C(sp(2))-H functionalization of N-aryl amines with various sodium salts | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000508570400011 | - |
dc.identifier.doi | 10.1039/c9ob02217a | - |
dc.identifier.bibliographicCitation | ORGANIC & BIOMOLECULAR CHEMISTRY, v.18, no.3, pp.450 - 464 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.scopusid | 2-s2.0-85078458213 | - |
dc.citation.endPage | 464 | - |
dc.citation.startPage | 450 | - |
dc.citation.title | ORGANIC & BIOMOLECULAR CHEMISTRY | - |
dc.citation.volume | 18 | - |
dc.citation.number | 3 | - |
dc.contributor.affiliatedAuthor | Mudithanapelli, Chandrashekar | - |
dc.contributor.affiliatedAuthor | Kim, Mi-hyun | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | C-H FUNCTIONALIZATION | - |
dc.subject.keywordPlus | VISIBLE-LIGHT | - |
dc.subject.keywordPlus | BRUCINE | - |
dc.subject.keywordPlus | JULOLIDINE | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | REAGENTS | - |
dc.subject.keywordPlus | ARENES | - |
dc.subject.keywordPlus | DYES | - |
dc.subject.keywordPlus | TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | ACETYLCHOLINE | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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