Rational design of Cu-doped Co3O4@carbon nanocomposite and agriculture crop-waste derived activated carbon for high-performance hybrid supercapacitors
- Authors
- Pallavolu, Mohan Reddy; Krishna, Kurugundla Gopi; Nagaraju, Goli; Babu, P. S. Srinivasa; Sambasivam, Sangaraju; Sreedhar, Adem
- Issue Date
- Dec-2022
- Publisher
- ELSEVIER SCIENCE INC
- Keywords
- Hybrid composite; Cu-Co3O4; Nanocubes; Porous carbon; Hybrid supercapacitors; Energy density
- Citation
- JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.116, pp.428 - 437
- Journal Title
- JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
- Volume
- 116
- Start Page
- 428
- End Page
- 437
- URI
- https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/86874
- DOI
- 10.1016/j.jiec.2022.09.033
- ISSN
- 1226-086X
- Abstract
- Development of structurally stable transition metal-oxides and cost-effective biomass-based carbon materials have attracted considerable attention in the fabrication of hybrid supercapacitors. In this work, we designed spinal copper-doped cobalt oxide (Cu-Co3O4) nanoboxes decorated functionalized-carbon nanotubes (f-CNTs) as hybrid redox-type material and agriculture crop-waste derived mesoporous acti-vated carbon as capacitive-type electrode for high-performance hybrid supercapacitors. Structural prop-erties reveal that the Cu-Co3O4 has a cubic spinel structure and Raman spectra results confirm the presence of f-CNTs. The hybrid composite material demonstrates superior redox behavior with excellent structural durability. The hybrid electrodes exhibit maximum specific capacity of 130.7 mAh g(-1) at 0.5 A g(-1) with 86.7 % capacitance retention over 10,000 cycles. Besides, the crop waste-derived activated car-bon demonstrates high surface area (1549 m2g(-1)), mesoporous characteristics and excellent capacitive behavior. The high voltage hybrid supercapacitor is further fabricated with Cu-Co3O4 @F-CNTs as battery-type and biomass-derived activated carbon as capacitive-type electrodes, which demonstrate high energy density of 30.8 Wh kg-1 at 5972 W kg(-1) power density. The augmented results indicate that the hybrid composites with biomass-derived carbon materials pave the way for design of eco-friendly energy storage applications. (c) 2022 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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