Asymmetric supercapacitors based on biomass-derived porous activated carbon (PAC)/1D manganese oxide (MnO2) electrodes with high power and energy densities

Abstract

In this study, we present the electrochemical performance of an asymmetric supercapacitor (ASC) composed of one-dimensional manganese oxide (MnO2) nanorods embedded in porous activated carbon sheets (MnO2/PAC) as the positive electrode (positrode), and renewable porous activated carbon (PAC) as the negative electrode (negatrode). This configuration facilitates a high rate of charge/discharge while maintaining substantial specific capacity. The MnO2/PAC composite was successfully synthesized using a hydrothermal technique, while the PAC material was produced through pyrolysis reaction. The MnO2/PAC composite exhibited a maximum specific capacitance of 208.75F g-1 at 0.5 A/g and demonstrated a cyclic stability of 87.43 % in neutral aqueous electrolytes. This notable electrochemical performance is attributed to the significant contribution of the high pseudo-capacitance offered by dense MnO2 nanorods, in addition to the expansive surface area of the activated carbon sheets with closely packed structures. The ASC constructed as PAC//MnO2/PAC displayed a high energy density of 23.3 Wh kg-1 and a power density of 350.4 W kg-1 at a current density of 0.5 A/g. Furthermore, the device showcased exceptional cycling stability, retaining 90.3 % at a current density of 4 A/g. These results underscore the substantial untapped potential of ASC devices for innovative applications in advanced energy storage.