Waterproof, Highly Tough, and Fast Self-Healing Polyurethane for Durable Electronic Skin
- Authors
- Ying, Wu Bin; Yu, Zhe; Kim, Do Hwan; Lee, Kyung Jin; Hu, Han; Liu, Yiwei; Kong, Zhengyang; Wang, Kai; Shang, Jie; Zhang, Ruoyu; Zhu, Jin; Li, Run-Wei
- Issue Date
- Mar-2020
- Publisher
- AMER CHEMICAL SOC
- Keywords
- polyurethane; toughness; water proof; self-healing; electronic skin
- Citation
- ACS APPLIED MATERIALS & INTERFACES, v.12, no.9, pp.11072 - 11083
- Indexed
- SCIE
SCOPUS
- Journal Title
- ACS APPLIED MATERIALS & INTERFACES
- Volume
- 12
- Number
- 9
- Start Page
- 11072
- End Page
- 11083
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/10640
- DOI
- 10.1021/acsami.0c00443
- ISSN
- 1944-8244
- Abstract
- A stretchable electronic skin (e-skin) requires a durable elastomeric matrix to serve in various conditions. Therefore, excellent and balanced properties such as elasticity, water proof capability, toughness, and self-healing are demanded. However, it is very difficult and often contradictory to optimize them at one time. Here, a polyurethane (BS-PU-3) containing a polydisperse hard segment, hydrophobic soft segment, and a dynamic disulfide bond was prepared by one-pot synthesis. Unlike the normal two-pot reaction, BS-PU-3 obtained through the one-pot method owned a higher density of self-healing points along the main chain and a faster self-healing speed, which reached 1.11 mu m/min in a cut-through sample and recovered more than 93% of virgin mechanical properties in 6 h at room temperature. Moreover, a remarkable toughness of 27.5 MJ/m(3) assures its durability as an e-skin matrix. Even with a 1 mm notch (half of the total width) on a standard dumbbell specimen, it could still bear the tensile strain up to 324% without any crack propagation. With polybutadiene as the soft segment, the shape, microstructure, and conductivity in BS-PU-3 and BS-PU-3-based stretchable electronics kept very stable after soaking in water for 3 days, proving the super waterproof property. An e-skin demo was constructed, and self-healing in pressure sensitivity, mechanical, and electrical properties were verified.
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