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Co₃O₄-loaded ZnO nanofibers for excellent hydrogen sensingCo3O4-loaded ZnO nanofibers for excellent hydrogen sensing

Other Titles
Co3O4-loaded ZnO nanofibers for excellent hydrogen sensing
Authors
Lee, Jae-HyoungKim, Jin-YoungKim, Jae-HunMirzaei, AliKim, Hyoun WooKim, Sang Sub
Issue Date
Oct-2019
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
ZnO; Co3O4; Nanofiber; Gas sensor; Sensing mechanism
Citation
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v.44, no.50, pp.27499 - 27510
Indexed
SCIE
SCOPUS
Journal Title
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume
44
Number
50
Start Page
27499
End Page
27510
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/12500
DOI
10.1016/j.ijhydene.2019.08.226
ISSN
0360-3199
Abstract
The development of outstanding H-2 -sensing materials is vital for the realization of eco-friendly devices using H-2-based energy. ZnO nanofibers have excellent H-2-sensing performance. In this study, we synthesized a series of Co3O4-loaded ZnO nanofibers with the formula (1-x)ZnO-xCo(3)O(4)(x = 0.03, 0.05, 0.1, and 0.15, representing the molar ratio of Co3O4) via electrospinning to improve the H-2-sensing properties of pristine nanofibers. The sensing results indicated that a sensor with a nominal composition of 0.95ZnO-0.05Co(3)O(4) had the highest response of similar to 133 to 10 ppm H-2 gas, with good H-2 selectivity. The main mechanisms underlying the excellent H-2-sensing capability of the optimized gas sensor involved ZnO surface/grain boundaries and Co3O4.
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