Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics
- Authors
- Kim, Dong Sub; Chang, Jinho; Leem, Soojung; Park, Jung Su; Thordarson, Pall; Sessler, Jonathan L
- Issue Date
- Dec-2015
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.51, pp.16038 - 16042
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 137
- Number
- 51
- Start Page
- 16038
- End Page
- 16042
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/142997
- DOI
- 10.1021/jacs.5b06524
- ISSN
- 0002-7863
- Abstract
- Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P1) and phenyl C-61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
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