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Cited 63 time in webofscience Cited 64 time in scopus
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Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics

Authors
Kim, Dong SubChang, JinhoLeem, SoojungPark, Jung SuThordarson, PallSessler, Jonathan L
Issue Date
Dec-2015
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.51, pp.16038 - 16042
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume
137
Number
51
Start Page
16038
End Page
16042
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/142997
DOI
10.1021/jacs.5b06524
ISSN
0002-7863
Abstract
Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P1) and phenyl C-61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
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