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Silver(I)-Mediated C-H Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude
- Authors
- Youn, So Won; Ko, Tae Yun; Jang, Min Jung; Jang, Su San
- Issue Date
- Jan-2015
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- cyclization; indoles; migration; oxidation; silver
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v.357, no.1, pp.227 - 234
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED SYNTHESIS & CATALYSIS
- Volume
- 357
- Number
- 1
- Start Page
- 227
- End Page
- 234
- ISSN
- 1615-4150
- Abstract
- A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of beta-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.
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Related Researcher
- Youn, So Won
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)