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Total Synthesis of (+/-)-Lycorine from the Endo-Cycloadduct of 3,5-Dibromo-2-pyrone and (E)-beta-Borylstyrene
- Issue Date
- Nov-2014
- Publisher
- American Chemical Society
- Citation
- Organic Letters, v.16, no.21, pp 5718 - 5720
- Pages
- 3
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Organic Letters
- Volume
- 16
- Number
- 21
- Start Page
- 5718
- End Page
- 5720
- ISSN
- 1523-7060
1523-7052
- Abstract
- A new synthetic route to (+/-)-lycorine, starting from the endo-cycloadduct of 3,5-dibromo-2-pyrone and (E)-beta-borylstyrene, is reported. Boronate oxidation and a set of reactions including face-selective epoxidation provided the pivotal C1-OH group and C3/C3a double bond.
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Related Researcher
- Cho, Cheon Gyu
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)