Semi-crystalline photovoltaic polymers with efficiency exceeding 9% in a similar to 300 nm thick conventional single-cell deviceopen access
- Authors
- Nguyen, Thanh Luan; Choi, Hyosung; Ko, Seo-jin; Uddin, Mohammad Afsar; Walker, Bright; Yum, Seungjib; Jeong, Ji-eun; Yun, Myoung-hee; Shin, Tae Joo; Hwang, Sungu; Kim, Jinyoung; Woo, Han Young
- Issue Date
- Jul-2014
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- ENERGY & ENVIRONMENTAL SCIENCE, v.7, no.9, pp.3040 - 3051
- Indexed
- SCIE
SCOPUS
- Journal Title
- ENERGY & ENVIRONMENTAL SCIENCE
- Volume
- 7
- Number
- 9
- Start Page
- 3040
- End Page
- 3051
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/143344
- DOI
- 10.1039/C4EE01529K
- ISSN
- 1754-5692
- Abstract
- We report a series of semi-crystalline, low band gap (LBG) polymers and demonstrate the fabrication of highly efficient polymer solar cells (PSCs) in a thick single-cell architecture. The devices achieve a power conversion efficiency (PCE) of over 7% without any post-treatment (annealing, solvent additive, etc.) and outstanding long-term thermal stability for 200 h at 130 degrees C. These excellent characteristics are closely related to the molecular structures where intra-and/or intermolecular noncovalent hydrogen bonds and dipole-dipole interactions assure strong interchain interactions without losing solution processability. The semi-crystalline polymers form a well-distributed nano-fibrillar networked morphology with PC70BM with balanced hole and electron mobilities (a h/e mobility ratio of 1-2) and tight interchain packing (a pi-pi stacking distance of 3.57-3.59 A) in the blend films. Furthermore, the device optimization with a processing additive and methanol treatment improves efficiencies up to 9.39% in a similar to 300 nm thick conventional single-cell device structure. The thick active layer in the PPDT2FBT: PC70BM device attenuates incident light almost completely without damage in the fill factor (0.71-0.73), showing a high short-circuit current density of 15.7-16.3 mA cm(-2). Notably, PPDT2FBT showed negligible changes in the carrier mobility even at similar to 1 mm film thickness.
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