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(E)-beta-Borylstyrene in the Diels-Alder Reaction with 3,5-Dibromo-2-pyrone for the Syntheses of (+/-)-1-epi-Pancratistatin and (+/-)- Pancratistatin
- Authors
- Cho, Hyun-Kyu; Lim, Hwa-Yeon; Cho, Cheon-Gyu
- Issue Date
- Nov-2013
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.15, no.22, pp.5806 - 5809
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 15
- Number
- 22
- Start Page
- 5806
- End Page
- 5809
- ISSN
- 1523-7060
- Abstract
- New synthetic routes to (+/-)-1-epi-pancratistatin and (+/-)-pancratistatin were devised using (E)-beta-borylstyrene as a dienophile for the key Diels-Alder reaction with 3,5-dibromo-2-pyrone. The boronate in the cycloadduct was oxidized to provide the pivotal C1-hydroxyl group of the titled compounds.
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Collections - 서울 자연과학대학 > 서울 화학과 > 1. Journal Articles
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Related Researcher
- Cho, Cheon Gyu
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)