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Gold Carbenes from Substituted Propargyl Acetates: Intramolecular Ene-type Reactions to 2-Acetoxynaphthalene Derivatives
- Authors
- Oh, Chang Ho; Kim, Ji Hee; Piao, Lanhua; Yu, Jin; Kim, So Young
- Issue Date
- Aug-2013
- Publisher
- John Wiley & Sons Ltd.
- Keywords
- carbenes; catalysis; cycloisomerization; ene reaction; gold; propargyl carboxylate
- Citation
- Chemistry - A European Journal, v.19, no.32, pp 10501 - 10505
- Pages
- 5
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Chemistry - A European Journal
- Volume
- 19
- Number
- 32
- Start Page
- 10501
- End Page
- 10505
- ISSN
- 0947-6539
1521-3765
- Abstract
- A new Au-catalyzed cascade reaction was developed for the conversion of propargylic acetates 1 to benzannulated products 2 in good to excellent yields. The gold catalyst is involved in generating intermediate A and in the ene-type reaction of intermediate B for the formation of product 2 (see scheme).
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