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Selective Construction of Aliphatic Polycycles Utilizing Platinum-Catalyzed Cyclization of 2-(Enynyl)cycloalkenals
- Authors
- Han, Jin Wook; Lee, Ji Ho; Oh, Chang Ho
- Issue Date
- Jul-2013
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- cyclization; homogeneous catalysis; platinum; carbenes; carbocycles
- Citation
- SYNLETT, v.24, no.11, pp.1433 - 1437
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNLETT
- Volume
- 24
- Number
- 11
- Start Page
- 1433
- End Page
- 1437
- ISSN
- 0936-5214
- Abstract
- An efficient method for the selective construction of aliphatic polycycles through platinum-catalyzed cyclization of 2-(enynyl) cycloalkenals has been developed by considering electronic (ligand) and structural (olefinic tether) effect. The presence or absence of ligand and the length of olefinic tether determine the course of the reaction after the formation of platinum-carbene complex, so that four types of aliphatic polycycles can be formed selectively.
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Related Researcher
- Oh, Chang Ho
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)