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Entry to beta-Alkoxyacrylates via Gold-Catalyzed Intermolecular Coupling of Alkynoates and Allylic Ethers
- Authors
- Park, Sae Rom; Kim, Cheoljae; Kim, Dong-gil; Thrimurtulu, Neetipalli; Yeom, Hyun-Suk; Jun, Jungho; Shin, Seunghoon; Rhee, Young Ho
- Issue Date
- Mar-2013
- Publisher
- American Chemical Society
- Citation
- Organic Letters, v.15, no.6, pp 1166 - 1169
- Pages
- 4
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Organic Letters
- Volume
- 15
- Number
- 6
- Start Page
- 1166
- End Page
- 1169
- ISSN
- 1523-7060
1523-7052
- Abstract
- The first gold-catalyzed Intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted beta-alkoxyacrylates in a highly efficient manner.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)