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Au(I)-catalyzed intramolecular oxidative cyclopropanation of 1,6-enynes derived from propiolamides with diphenyl sulfoxide
- Authors
- Yeom, Hyun-Suk; Shin, Seunghoon
- Issue Date
- Feb-2013
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY, v.11, no.7, pp.1089 - 1092
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC & BIOMOLECULAR CHEMISTRY
- Volume
- 11
- Number
- 7
- Start Page
- 1089
- End Page
- 1092
- ISSN
- 1477-0520
- Abstract
- We have developed gold(I)-catalyzed oxidative cyclopropanation of 1,6-enynes derived from propiolamides employing diphenyl sulfoxide as an oxidant. 1,6-Enynes having a terminal alkyne and a propiolamide tether efficiently transformed into cyclopropane carboxaldehyde derivatives.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)