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Total Synthesis of 1-Oxomiltirone and Arucadiol

Authors
Seong, ChaehyeonKang, JuyeonChai, UiseongMac, Dinh HungOh, Chang Ho
Issue Date
Dec-2020
Publisher
GEORG THIEME VERLAG KG
Keywords
arucadiol; 1-oxomiltirone; [4+2]-benzannulation; gold(III) bromide; copper(II) trifluoromethanesulfonate
Citation
SYNLETT, v.31, no.19, pp.1953 - 1956
Indexed
SCIE
SCOPUS
Journal Title
SYNLETT
Volume
31
Number
19
Start Page
1953
End Page
1956
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/144215
DOI
10.1055/s-0039-1690743
ISSN
0936-5214
Abstract
A practical and efficient approach for the total synthesis of arucadiol and 1-oxomiltirone is reported. The key step which involves an intramolecular [4+2] cycloaddition catalyzed by gold(III) bromide or copper(II) triflate leads to the formation of 6-6-6-fused aromatic abietane core.
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