3D nanoweb-like zeolitic imidazole framework in a microfluidic system for catalytic applications
- Authors
- Ko, Dong-Hyeon; Chen, Rui; Sun, Dengrong; Leem, Jin Woo; Joo, Jeong-Un; Kang, Il-Suk; Sung, Myung Mo; Lee, Haiwon; Kim, Dong-Pyo
- Issue Date
- Jun-2020
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- REACTION CHEMISTRY & ENGINEERING, v.5, no.6, pp.1129 - 1134
- Indexed
- SCIE
SCOPUS
- Journal Title
- REACTION CHEMISTRY & ENGINEERING
- Volume
- 5
- Number
- 6
- Start Page
- 1129
- End Page
- 1134
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/145648
- DOI
- 10.1039/d0re00004c
- ISSN
- 2058-9883
- Abstract
- A 3D nanoweb-like zeolite imidazole framework (ZIF-8) as an efficient heterogeneous catalyst was structured inside a functionalized microfluidic channel by immobilizing the ZIF on 3D carbon nanotube (CNT) networks across the gap among the built-in micropillars for the Knoevenagel condensation reaction. The quantitative conversion was achieved under mild conditions of ethanol solvent and room temperature. The ZIF-8 3D nanoweb systems showed higher conversion than the identical systems without CNT-based networks which indicates the catalytic superiority of 3D nanoweb structures.
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