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3D nanoweb-like zeolitic imidazole framework in a microfluidic system for catalytic applications

Authors
Ko, Dong-HyeonChen, RuiSun, DengrongLeem, Jin WooJoo, Jeong-UnKang, Il-SukSung, Myung MoLee, HaiwonKim, Dong-Pyo
Issue Date
Jun-2020
Publisher
ROYAL SOC CHEMISTRY
Citation
REACTION CHEMISTRY & ENGINEERING, v.5, no.6, pp.1129 - 1134
Indexed
SCIE
SCOPUS
Journal Title
REACTION CHEMISTRY & ENGINEERING
Volume
5
Number
6
Start Page
1129
End Page
1134
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/145648
DOI
10.1039/d0re00004c
ISSN
2058-9883
Abstract
A 3D nanoweb-like zeolite imidazole framework (ZIF-8) as an efficient heterogeneous catalyst was structured inside a functionalized microfluidic channel by immobilizing the ZIF on 3D carbon nanotube (CNT) networks across the gap among the built-in micropillars for the Knoevenagel condensation reaction. The quantitative conversion was achieved under mild conditions of ethanol solvent and room temperature. The ZIF-8 3D nanoweb systems showed higher conversion than the identical systems without CNT-based networks which indicates the catalytic superiority of 3D nanoweb structures.
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