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Enantioselective Dearomative Cyclization of Homotryptamines with Allenamides into Indolo[2,3-b]quinolines
- Issue Date
- Apr-2020
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- dearomative cyclization; homotryptamine; indolo[2; 3-b]quinolines; chiral Bronsted acid catalysis
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v.362, no.9, pp.1841 - 1845
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED SYNTHESIS & CATALYSIS
- Volume
- 362
- Number
- 9
- Start Page
- 1841
- End Page
- 1845
- ISSN
- 1615-4150
- Abstract
- We have developed a catalytic asymmetric dearomative cyclization of homotryptamine derivatives, furnishing enantioenriched indolo[2,3-b]quinoline scaffolds. The activation of allenamides in the presence of chiral phosphoric acids triggered the dearomative cyclization in up to 99% ee.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)