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Acid-Catalyzed [3,3] Sigmatropic Rearrangement of N-Cbz-Diaryl Hydrazide for the Synthesis of Mono-N-Cbz-1,1 '-biaryl-2,2 '-diamine
- Issue Date
- Jan-2011
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Sigmatropic rearrangement; Hydrazides; Cross-coupling; Biaryls; Amines
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2011, no.3, pp.455 - 457
- Indexed
- SCIE
SCOPUS
- Journal Title
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 2011
- Number
- 3
- Start Page
- 455
- End Page
- 457
- ISSN
- 1434-193X
- Abstract
- N-Cbz-Diaryl hydrazides undergo acid-catalyzed [3,3] sigmatropic rearrangement to afford N-Cbz-1,1'-biaryl-2,2'-diamines. The resultant products can be versatile synthetic platforms for a wide variety of C-2- and/or nonsymmetric axially chiral ligands and organocatalysts.
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Related Researcher
- Cho, Cheon Gyu
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)