One-Pot Sequential N-Heterocyclic Carbene/Rhodium(III) Catalysis: Synthesis of Fused Polycyclic Isocoumarins
- Authors
- Youn, So Won; Yoo, Huen Ji
- Issue Date
- Jul-2017
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- benzo-fused lactones; C-H activation; one-pot sequential catalysis; organocatalysis; rhodium catalysis
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v.359, no.13, pp.2176 - 2183
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED SYNTHESIS & CATALYSIS
- Volume
- 359
- Number
- 13
- Start Page
- 2176
- End Page
- 2183
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/152046
- DOI
- 10.1002/adsc.201700072
- ISSN
- 1615-4150
- Abstract
- A one-pot sequential N-heterocyclic carbene-rhodium (NHC-Rh) catalysis is described, demonstrating the compatibility of NHC and Rh catalysts. N-Heterocyclic carbene-catalyzed aerobic oxidation of benzaldehydes and subsequent rhodium(III)-catalyzed oxidative coupling/ annulation with multiple bonds enabled the formation of two C-O bonds and one C-C bond in a single pot. This operationally easy, one-pot protocol under air provides access to a diverse array of valuable fused polycyclic isocoumarins.
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