Palladium-Catalyzed Regioselective Synthesis of 3-Arylindoles from N-Ts-Anilines and Styrenes
- Authors
- Youn, So Won; Ko, Tae Yun; Jang, Young Ho
- Issue Date
- Jun-2017
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- C-H activation; homogeneous catalysis; indoles; palladium; regioselectivity
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.23, pp.6636 - 6640
- Indexed
- SCIE
SCOPUS
- Journal Title
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Volume
- 56
- Number
- 23
- Start Page
- 6636
- End Page
- 6640
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/152244
- DOI
- 10.1002/anie.201702205
- ISSN
- 1433-7851
- Abstract
- A Pd-catalyzed intermolecular oxidative annulation between N-Ts-anilines and styrenes was developed. This method offers a straightforward and robust approach to a wide range of 3-arylindoles using readily available starting materials with good functional-group tolerance and high regioselectivity and efficiency. Further elaboration of the products obtained from this process provided access to highly functionalized and structurally diverse indoles, for example, 3-(indol-3-yl)carbazoles, 1,9-dihydropyrrolo-[2,3-b]carbazoles, and 3'-aryl-3,5'-biindoles.
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