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Preparation of high purity silica originated from rice husks by chemically removing metallic impurities

Authors
Lee, Jin HyungKwon, Jeong HeoLee, Jae-WonLee, Hye-sunChang, Jeong HoSang, Byoung-In
Issue Date
Jun-2017
Publisher
한국공업화학회
Keywords
Rice husk; Biosilica; Chemical treatment; Ionic liquid; Bioconversion
Citation
Journal of Industrial and Engineering Chemistry, v.50, pp 79 - 85
Pages
7
Indexed
SCIE
SCOPUS
KCI
Journal Title
Journal of Industrial and Engineering Chemistry
Volume
50
Start Page
79
End Page
85
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/152294
DOI
10.1016/j.jiec.2017.01.033
ISSN
1226-086X
1876-794X
Abstract
Chemical treatments were used to synthesize high-purity silica from rice husk. A comparative study was carried out by using four chemicals: sulfuric acid, hydrogen chloride, oxalic acid, and ionic liquid (1-butyl-3-methylimidazolium hydrogen sulfate). The ash content significantly increased in sulfuric-acid and the ionic liquid treatments with the removal of both cellulose and hemicellulose. Drastic increases of silica purity were observed in samples treated with sulfuric acid and the ionic liquid at 99.6% and 99.5%, respectively. Furthermore, the ionic liquid treatment increased the surface area and pore volume by 1.9 times and 2.4 times, respectively, with respect to the sample not subjected to chemical treatment.
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