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MnCo₂O₄ spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditions

Authors
Mishra, Dinesh KumarLee, Hye JinKim, JinsungLee, Hong-ShikCho, Jin KuSuh, Young-WoongYi, YongjinKim, Yong Jin
Issue Date
Apr-2017
Publisher
ROYAL SOC CHEMISTRY
Citation
GREEN CHEMISTRY, v.19, no.7, pp.1619 - 1623
Indexed
SCIE
SCOPUS
Journal Title
GREEN CHEMISTRY
Volume
19
Number
7
Start Page
1619
End Page
1623
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/152622
DOI
10.1039/c7gc00027h
ISSN
1463-9262
Abstract
A new class of MnCo2O4 spinel supported Ru catalyst, Ru/MnCo2O4, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo2O4 having both Lewis and Bronsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.
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