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Alkyl Side-Chain Engineering in Wide-Bandgap Copolymers Leading to Power Conversion Efficiencies over 10%

Authors
Liu, TaoPan, XuexueMeng, XiangyiLiu, YuWei, DonghuiMa, WeiHuo, LijunSun, XiaoboLee, Tack HoHuang, MinjuanChoi, HyosungKim, Jin YoungChoy, Wallace C. H.Sun, Yanming
Issue Date
Feb-2017
Publisher
WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords
alkyl side chain; efficiency; organic solar cells; wide-bandgap copolymers
Citation
Advanced Materials, v.29, no.6
Indexed
SCI
SCIE
SCOPUS
Journal Title
Advanced Materials
Volume
29
Number
6
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/152974
DOI
10.1002/adma.201604251
ISSN
0935-9648
1521-4095
Abstract
A series of wide-bandgap (WBG) copolymers with different alkyl side chains are synthesized. Among them, copolymer PBT1-EH with moderatly bulky side chains on the acceptor unit shows the best photovoltaic performance with power conversion efficiency over 10%. The results suggest that the alkyl side-chain engineering is an effective strategy to further tuning the optoelectronic properties of WBG copolymers.
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