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A Formal Synthesis of Komaroviquinone: Use of a Pt-Catalyzed Hydrative Cyclization Reaction
- Authors
- Oh, Chang Ho; Piao, Lanhua; Jung, Jaemun; Kim, Jaewoong
- Issue Date
- Oct-2016
- Publisher
- Wiley - VCH Verlag GmbH & Co. KG
- Keywords
- cyclization; enynals; komaroviquinone; natural products; total synthesis
- Citation
- Asian Journal of Organic Chemistry, v.5, no.10, pp 1237 - 1241
- Pages
- 5
- Indexed
- SCIE
SCOPUS
- Journal Title
- Asian Journal of Organic Chemistry
- Volume
- 5
- Number
- 10
- Start Page
- 1237
- End Page
- 1241
- ISSN
- 2193-5807
2193-5815
- Abstract
- A formal synthesis of komaroviquinone has been accomplished by utilizing the Pt-catalyzed hydrative cyclization of an enynal that was easily prepared in a convergent manner. The Pt-catalyzed hydrative cyclization reaction afforded the corresponding tricyclic product, which was utilized in the synthesis of a known precursor that led to the formation of komaroviquinone through an additional four-step synthesis.
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