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Synthesis, Characterization and TFT Characteristics of Diketopyrrolopyrrole Based Copolymer

Authors
Bathula, ChinnaJeong, SeunghoonChung, JeyonKang, Youngjong
Issue Date
Mar-2016
Publisher
AMER SCIENTIFIC PUBLISHERS
Keywords
Benzodithiophene; DPP; TFT; Conjugate Copolymers
Citation
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.16, no.3, pp.2796 - 2799
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume
16
Number
3
Start Page
2796
End Page
2799
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/155023
DOI
10.1166/jnn.2016.11099
ISSN
1533-4880
Abstract
A novel diketopyrrolopyrrole (DPP) based low band gap polymer, poly[4,8-bis(triisopropylsilylethynyl) benzo[1,2-b:4,5-b!]dithiophene-2,6-diyl-alt-[2,5-di-hexyl-3,6-dithiophen-2-ylpyrrolo[3,4-c]pyrrole-1,4-dione] (PTIPSBDT-DPP) is synthesized by Stille polymerization for use in thin film transistor (TFTs). The new polymer contain extended aromatic pi-conjugated segments alternating with the DPP units and are designed to increase the free energy for charge generation to overcome current limitations in photocurrent generation. In this study we describe the synthesis, thermal stability, optical, electrochemical properties and TFT characteristics.
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