Synthesis, Characterization and TFT Characteristics of Diketopyrrolopyrrole Based Copolymer
- Authors
- Bathula, Chinna; Jeong, Seunghoon; Chung, Jeyon; Kang, Youngjong
- Issue Date
- Mar-2016
- Publisher
- AMER SCIENTIFIC PUBLISHERS
- Keywords
- Benzodithiophene; DPP; TFT; Conjugate Copolymers
- Citation
- JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.16, no.3, pp.2796 - 2799
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
- Volume
- 16
- Number
- 3
- Start Page
- 2796
- End Page
- 2799
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/155023
- DOI
- 10.1166/jnn.2016.11099
- ISSN
- 1533-4880
- Abstract
- A novel diketopyrrolopyrrole (DPP) based low band gap polymer, poly[4,8-bis(triisopropylsilylethynyl) benzo[1,2-b:4,5-b!]dithiophene-2,6-diyl-alt-[2,5-di-hexyl-3,6-dithiophen-2-ylpyrrolo[3,4-c]pyrrole-1,4-dione] (PTIPSBDT-DPP) is synthesized by Stille polymerization for use in thin film transistor (TFTs). The new polymer contain extended aromatic pi-conjugated segments alternating with the DPP units and are designed to increase the free energy for charge generation to overcome current limitations in photocurrent generation. In this study we describe the synthesis, thermal stability, optical, electrochemical properties and TFT characteristics.
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