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Synthesis and electronic properties of thiadiazole[3,4-c]pyridine copolymers for solar cell application

Authors
Bathula, ChinnaKalode, PranavPatil, SupriyaLee, Sang KyuBelavagi, Ningaraddi S.Khazi, Imtiyaz AhmedKang, Youngjong
Issue Date
Mar-2016
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Organic solar cell; Thiadiazolo pyridine; Organic electronics; Conjugated polymers; Stille reaction
Citation
TETRAHEDRON LETTERS, v.57, no.9, pp.998 - 1002
Indexed
SCIE
SCOPUS
Journal Title
TETRAHEDRON LETTERS
Volume
57
Number
9
Start Page
998
End Page
1002
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/155034
DOI
10.1016/j.tetlet.2016.01.063
ISSN
0040-4039
Abstract
Two novel conjugated polymers P1, P2 containing dithienothiadiazole[3,4-c]pyridine acceptor and benzodithiophene, naphthodithiophene donors were synthesized by Stille reaction. The polymers were characterized by H-1 NMR, GPC, and elemental analysis. The optical band gaps for Pl, P2 were found to be 1.67 and 1.60 eV. The electrochemical studies of P1, P2 revealed the HOMO and LUMO energy levels of the polymer were -5.07, -5.13 eV, and -3.40, -3.53 eV respectively. The polymers are thermally stable up to 380-405 degrees C. Optoelectronic investigation and electrical properties of fabricated organic field effect transistor (OFET) suggest these polymers can be potential candidates for organic solar cell application.
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