The cooperative FeCl3/DDQ system for the regioselective synthesis of 3-arylindoles from beta-monosubstituted 2-alkenylanilines
- Authors
- Jang, Su San; Youn, So Won
- Issue Date
- Feb-2016
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY, v.14, no.7, pp.2200 - 2204
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC & BIOMOLECULAR CHEMISTRY
- Volume
- 14
- Number
- 7
- Start Page
- 2200
- End Page
- 2204
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/155151
- DOI
- 10.1039/c6ob00074f
- ISSN
- 1477-0520
- Abstract
- A highly regioselective synthesis of 3-arylindoles by using the cooperative FeCl3/DDQ system has been developed. This new protocol represents an attractive route for the synthesis of 3-arylindoles from readily accessible non-indole precursors, beta-arylsubstituted 2-styrylanilines, using an inexpensive catalyst and oxidant. Noteworthy is the unique synergetic and synergistic effect of FeCl3 and DDQ on the 1,2-aryl migratory process.
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