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Deoxygenation of oleic acid over Ce(1-x)Zr(x)O2 catalysts in hydrogen environment
- Authors
- Shim, Jae-Oh; Jeong, Dae-Woon; Jang, Won-Jun; Jeon, Kyung-Won; Jeon, Byong Hun; Cho, Seung Yeon; Roh, Hyun-Seog; Na, Jeong-Geol; Ko, Chang Hyun; Oh, You-Kwan; Han, Sang Sub
- Issue Date
- May-2014
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Ce(1–x)Zr(x)O2; Deoxygenation (DO); Oleic acid; Reducibility
- Citation
- RENEWABLE ENERGY, v.65, no.Special SI, pp.36 - 40
- Indexed
- SCIE
SCOPUS
- Journal Title
- RENEWABLE ENERGY
- Volume
- 65
- Number
- Special SI
- Start Page
- 36
- End Page
- 40
- ISSN
- 0960-1481
- Abstract
- Ce(1-x)Zr(x)O2 catalysts were prepared by co-precipitation method for deoxygenation (DO) of oleic acid. The CeO2/ZrO2 ratio was systematically varied to optimize Ce(1-x)Zr(x)O2 catalysts. Ce0.6Zr0.4O2 exhibited the highest oleic acid conversion as well as high selectivity to C-9 similar to C-17 compounds (diesel fuel range) at the reaction temperature of 300 degrees C. The high activity/selectivity of Ce0.6Zr0.4O2 catalyst was correlated to its reducibility, oxygen storage capacity and crystallite size.
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Related Researcher
- Jeon, Byong Hun
- COLLEGE OF ENGINEERING (DEPARTMENT OF EARTH RESOURCES AND ENVIRONMENTAL ENGINEERING)