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Nitridated Si-Ti-Ni alloy as an anode for Li rechargeable batteries

Authors
Song, TaeseupKil, Ki ChunJeon, YeryoungLee, SangkyuShin, Woo CheolChung, ByungjooKwon, KyungjungPaik, Ungyu
Issue Date
May-2014
Publisher
Elsevier BV
Keywords
Silicon alloy; Nitridation; Anode; Li ion batteries
Citation
Journal of Power Sources, v.253, pp 282 - 286
Pages
5
Indexed
SCI
SCIE
SCOPUS
Journal Title
Journal of Power Sources
Volume
253
Start Page
282
End Page
286
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/160015
DOI
10.1016/j.jpowsour.2013.12.041
ISSN
0378-7753
1873-2755
Abstract
Nitridated Si-Ti-Ni (STN) ternary alloy as an anode for lithium ion batteries is prepared by the NH3 nitridation of STN alloy. The nitridated STN electrode shows 14% increased reversible capacity and 4 times higher rate capability at 3 C compared to those of pristine STN electrode. These improvements are attributed to the formation of nitride compounds (such as SiNx/SiNxOy, TiNx/TiNxOy and NiNx/NiNxOy) on STN alloy, which benefits both mechanics and kinetics.
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