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Influence of Citric Acid Molar Ratio on the Sintering Behavior of Nanocrystalline BaCe0.8Sm0.2O3-delta

Authors
Park, InyuKim, JeonginChoi, JinyiLee, HunhyeongPark, JonghunShin, Dongwook
Issue Date
May-2014
Publisher
AMER SCIENTIFIC PUBLISHERS
Keywords
Citric-Nitrate; Doped Barium Cerate; Nanocrystalline; Sintering Behavior
Citation
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.14, no.5, pp.3782 - 3785
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume
14
Number
5
Start Page
3782
End Page
3785
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/160018
DOI
10.1166/jnn.2014.7891
ISSN
1533-4880
Abstract
The samarium-doped barium cerate (BaCe0.8Sm0.2O3-delta, BCS) nano crystalline powders were synthesized via citric-nitrate method. The BCS nanopowders were prepared with various molar ratio of citric acid to metal nitrate. The pure perovskite structure was obtained from the BCS calcinated at 1200 degrees C and its crystalline size was increased with increase of the molar ratio citric acid to metal nitrate, while the aggregated particle size was significantly decreased as increasing the molar ratio. Also, excellent densification behavior was observed when high molar ratio of citric acid to metal nitrate was used. It was clarified that the molar ratio of citric acid determines the aggregated particle size and, in turn, finial microstructure after sintering.
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