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Improvement of the Cycling Performance of LiNi0.6Co0.2Mn0.2O2 Cathode Active Materials by a Dual-Conductive Polymer Coating

Authors
Ju, Sea HeeKang, Ik-SuLee, Yoon-SungShin, Won-KyungKim, SaheumShin, KyominKim, Dong-Won
Issue Date
Feb-2014
Publisher
AMER CHEMICAL SOC
Keywords
conductive polymer; surface modification; LiNi0.6Co0.2Mn0.2O2; protective coating; cycling performance
Citation
ACS APPLIED MATERIALS & INTERFACES, v.6, no.4, pp.2546 - 2552
Indexed
SCIE
SCOPUS
Journal Title
ACS APPLIED MATERIALS & INTERFACES
Volume
6
Number
4
Start Page
2546
End Page
2552
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/160776
DOI
10.1021/am404965p
ISSN
1944-8244
Abstract
LiNi0.6Co0.2Mn0.2O2 cathode materials were surface-modified by coating with a dual conductive poly(3,4-ethylenedioxythiophene)-co-poly(ethylene glycol) (PEDOT-co-PEG) copolymer, and their resulting electrochemical properties were investigated. The surface-modified LiNi0.6Co0.2Mn0.2O2 cathode material exhibited a high discharge capacity and good high rate performance due to enhanced transport of Li+ ions as well as electrons. The presence of a protective conducting polymer layer formed on the cathode also suppressed the growth of a resistive layer and inhibited the dissolution of transition metals from the active cathode materials, which resulted in more stable cycling characteristics than the pristine LiNi0.6Co0.2Mn0.2O2 cathode material at 55 degrees C.
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