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Synthesis and spectral properties of tetraquinoxalinoporphyrazines containing benzocrown-ether group

Authors
Song, Cheol JunJang, Chun KeunPark, Jong MinJung, Chang YoungYao, WangGu, Yeon JuJaung, Jae Yun
Issue Date
Nov-2013
Publisher
WORLD SCI PUBL CO INC
Keywords
tetraquinoxalinoporphyrazine; quinoxaline; Wittig reaction; alpha-diketone; benzo-crown-ether; chelating agent
Citation
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, v.17, no.11, pp.1134 - 1138
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume
17
Number
11
Start Page
1134
End Page
1138
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/161571
DOI
10.1142/S1088424613500946
ISSN
1088-4246
Abstract
The synthesis and spectral properties of the metal-free and the Mg complex derivatives of crown-substituted tetraquinoxalinoporphyrazine are described. Porphyrazine 4 and 5 have satisfactory solubility in chlorinated hydrocarbons, THF and toluene, but are practically insoluble in alcohols. Porphyrazine 5 generally did not show aggregation in CHCl3 but aggregate in DMF.
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