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Synthesis and spectral characterisation of dicyanopyrazine-related cyanoheterocycles

Authors
Song, Cheol JunJang, Chun KeunYao, WangJaung, Jae Yun
Issue Date
May-2013
Publisher
SAGE PUBLICATIONS LTD
Keywords
optical spectra; 2,3-naphthalene-dicarbonate; Wittig reaction; cyclic voltammetry; copper complex
Citation
JOURNAL OF CHEMICAL RESEARCH, no.5, pp.268 - 272
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF CHEMICAL RESEARCH
Number
5
Start Page
268
End Page
272
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/162907
DOI
10.3184/174751913X13642346476213
ISSN
1747-5198
Abstract
Four dicyanopyrazine-related cyanoheterocycles have been synthesised and characterised; they show different absorption maxima values and molar absorptivity in absorption spectra. HOMO and LUMO energy levels have been obtained by electrochemical measurements and DMol3 calculation and show little difference in HOMO values but big differences in LUMO values. Their UV-Vis absorbance and fluorescence spectra have been investigated in chloroform and toluene and their aggregation decreases as the concentration decreases in toluene.
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